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bicycle cleaning 101
Cleaning the Exposed Cables
Cleaning the exposed cables is another one of those minimal tasks that if neglected, can cause problems in the future. Much will depend on the area or climate where you live and ride. In warmer climates with high humidity, rust can appear on your cables in as quickly as a week. And don't forget the sweat factor. Now, this won't affect some of your newer bikes with internal cable routing. However, you will have exposed cable on your breaks and your derailleurs. I have seen these snap because of rust brought about by neglect. The process takes about two minutes of your time so take the time and add some protection.

1) This is one reason I like to use a water proof grease. Phil Woods is my favorite, but there are others. This is also something that you will want to do every week no matter what, even if you do not perform a total bike clean-up. It is not full-proof but it will help.
2) Prior to this step, you will want to remove any existing dirt or rus from the cables. This can be as simple as wiping down the cables with a cloth doused with some degreaser. If there is too much rust, you have to use other means. I do not recommend using sandpaper to remove the rust. If the cables are in poor condition, it would be easier to replace them. Cable only costs a few bucks. Otherwise, use bronze wool (which you can pick up at any hardware store) and some naval jelly (again at any hardware or boating store) to remove the rust. Use gloves as well.
3) After cleaning the cables, put a little grease between your fingers (photo 1) and run your fingers along all exposed cable (photo 2). This will put a light film along the cable and help ward off moisture until your next cleaning.